ASTM D5542-2004(2009) 离子色谱法分析高纯度水中痕量阴离子的标准试验方法
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【英文标准名称】:StandardTestMethodsforTraceAnionsinHighPurityWaterbyIonChromatography
【原文标准名称】:离子色谱法分析高纯度水中痕量阴离子的标准试验方法
【标准号】:ASTMD5542-2004(2009)
【标准状态】:现行
【国别】:美国
【发布日期】:2004
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:D19.03
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:
【英文主题词】:anion;eluant;ionchromatography;trace;Acetate;Anionscontent;Bromide(ion)analysis;Chlorideanalysis--waterapplications;Eluent/elution;Fluoride(ion)analysis;Formate;High-puritywater;Iodideion(soluble)content;Ionchromatography(IC
【摘要】:Theanionsfluoride,chloride,andsulfatehavebeenidentifiedasimportantcontributorstocorrosionofhighpressureboilers,electricpowerturbinesandtheirassociatedheatexchangers.Manyelectricpowerutilitiesattempttoreducethesecontaminantsintheirboilerfeedwatertolessthan1x03BC;g/L.Inthesemiconductormanufacturingprocesstheseions,amongothers,havebeenidentifiedasacauseoflowproductyieldand,thus,mustbemonitoredandcontrolledtolevelssimilartothoserequiredbytheelectricpowerindustry.Lowmolecularweightorganicacids,suchasacetateandformate,havebeenfoundinmanysteamgeneratorfeedwatersandcondensates.Theyarebelievedtocomefromthehightemperaturebreakdownoforganicmatterfoundinboilermakeupwater.ItisfeltthattheseorganicacidspromotecorrosionbyloweringthepHofboilerwatersandmayevenbecorrosivethemselves.Suchlowmolecularweightorganicsmayalsobeproducedwhenultravioletlightisusedtoproducebacteria-freewaterforsemiconductorprocessing.Suchpolarorganiccontaminantsaresuspectedofcausingreducedsemiconductoryields.Phosphatesarecommonlyaddedtodrumboilersinthelowmg/Lleveltoprecipitatecalciumandmagnesiumandtherebypreventscaleformation.Ionchromatographycanbeusedtomonitortheconcentrationofsuchchemicalsinboilerwater,aswellasdetectunwantedcarry-overintothesteam.1.1Thesetestmethodscoverthedeterminationoftrace(x03BC;g/L)levelsoffluoride,acetate,formate,chloride,phosphate,andsulfateinhighpuritywaterusingionchromatographyincombinationwithsamplepreconcentration.Otheranions,suchasbromide,nitrite,nitrate,sulfite,andiodidecanbedeterminedbythismethod.However,sincetheyarerarelypresentinsignificantconcentrationsinhighpuritywater,theyarenotincludedinthistestmethod.Twotestmethodsarepresentedandtheirrangesofapplication,asdeterminedbyacollaborativestudy,areasfollows:
RangeTested(x03BC;g/LAdded)
LimitofDetectionA(SingleOperator)(x03BC;g/L)
Sections
TestMethodA:
7x2013;15
Chloride
0x2013;24
0.8
Phosphate
0x2013;39
B
Sulfate
0x2013;55
1.8
TestMethodB:
16x2013;23
Fluoride
0x2013;14
0.7
【原文标准名称】:离子色谱法分析高纯度水中痕量阴离子的标准试验方法
【标准号】:ASTMD5542-2004(2009)
【标准状态】:现行
【国别】:美国
【发布日期】:2004
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:D19.03
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:
【英文主题词】:anion;eluant;ionchromatography;trace;Acetate;Anionscontent;Bromide(ion)analysis;Chlorideanalysis--waterapplications;Eluent/elution;Fluoride(ion)analysis;Formate;High-puritywater;Iodideion(soluble)content;Ionchromatography(IC
【摘要】:Theanionsfluoride,chloride,andsulfatehavebeenidentifiedasimportantcontributorstocorrosionofhighpressureboilers,electricpowerturbinesandtheirassociatedheatexchangers.Manyelectricpowerutilitiesattempttoreducethesecontaminantsintheirboilerfeedwatertolessthan1x03BC;g/L.Inthesemiconductormanufacturingprocesstheseions,amongothers,havebeenidentifiedasacauseoflowproductyieldand,thus,mustbemonitoredandcontrolledtolevelssimilartothoserequiredbytheelectricpowerindustry.Lowmolecularweightorganicacids,suchasacetateandformate,havebeenfoundinmanysteamgeneratorfeedwatersandcondensates.Theyarebelievedtocomefromthehightemperaturebreakdownoforganicmatterfoundinboilermakeupwater.ItisfeltthattheseorganicacidspromotecorrosionbyloweringthepHofboilerwatersandmayevenbecorrosivethemselves.Suchlowmolecularweightorganicsmayalsobeproducedwhenultravioletlightisusedtoproducebacteria-freewaterforsemiconductorprocessing.Suchpolarorganiccontaminantsaresuspectedofcausingreducedsemiconductoryields.Phosphatesarecommonlyaddedtodrumboilersinthelowmg/Lleveltoprecipitatecalciumandmagnesiumandtherebypreventscaleformation.Ionchromatographycanbeusedtomonitortheconcentrationofsuchchemicalsinboilerwater,aswellasdetectunwantedcarry-overintothesteam.1.1Thesetestmethodscoverthedeterminationoftrace(x03BC;g/L)levelsoffluoride,acetate,formate,chloride,phosphate,andsulfateinhighpuritywaterusingionchromatographyincombinationwithsamplepreconcentration.Otheranions,suchasbromide,nitrite,nitrate,sulfite,andiodidecanbedeterminedbythismethod.However,sincetheyarerarelypresentinsignificantconcentrationsinhighpuritywater,theyarenotincludedinthistestmethod.Twotestmethodsarepresentedandtheirrangesofapplication,asdeterminedbyacollaborativestudy,areasfollows:
RangeTested(x03BC;g/LAdded)
LimitofDetectionA(SingleOperator)(x03BC;g/L)
Sections
TestMethodA:
7x2013;15
Chloride
0x2013;24
0.8
Phosphate
0x2013;39
B
Sulfate
0x2013;55
1.8
TestMethodB:
16x2013;23
Fluoride
0x2013;14
0.7
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